Synthesis and characterization of NpCl4(DME)2 and PuCl4(DME)2 neutral transuranic An(IV) starting materials.
نویسندگان
چکیده
The 1,2-dimethoxyethane (DME) solvento adducts of Np(iv) and Pu(iv) tetrachloride have been prepared and isolated in good and moderate yields, respectively, along with single-crystal structural determinations. These neutral molecules are expected to provide alternative synthetic pathways in the pursuit of non-aqueous and organometallic complexes.
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عنوان ژورنال:
- Dalton transactions
دوره 43 4 شماره
صفحات -
تاریخ انتشار 2014